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The ceramic will tolerate the hight temps, the powder coater I talked to said powder coat will discolor in the 400* - 500* range.
I saw a kids motor that was powder coated white, but it turned pink after a few months.
Ceramic also acts as a heat barrier.
Mine were Jet-Hot brand and the headers look great, but the pipes were rusty in less than a year. They are re-doing them for me as long as I pay the shipping there.
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Brent Dolphin
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