Sometime ago, I did some research on boosting octane and found the information below. The link will take you to a great site that is most informative and a must read/reference guide.
Arthur
http://www.gnttype.org/techarea/misc/octanebooster.html
Toulene
R+M/2...114
Cost...$2.50/gal
Mixtures with 92 Octane Premium
10%...94.2 Octane
20%...96.4 Octane
30%...98.6 Octane
Notes: Common ingredient in Octane Boosters in a can. 12-16 ounces will only raise octane 2-3 *points*, I.e. from 92 to 92.3. Often costs $3-5 for 12-16 ounces, when it can be purchased for less than $3/gal at chemical supply houses or paint stores.